Abstract: Skin aging is a complex process influenced by oxidative stress, inflammation, and enzymatic activities that compromise essential proteins for structural integrity and promote hyperpigmentation. These processes result in wrinkles, loss of elasticity, and uneven skin tone making them central targets in cosmeceutical development. Conventional antioxidants and depigmenting agents often exhibit limitations such as instability and adverse effects thereby prompting the search for novel synthetic scaffolds with improved efficacy and safety. This study focused on the evaluation of arylated thiosemicarbazone derivatives as antioxidant agents for cosmetic applications. The primary goal was to determine their antioxidant properties. Specifically, antioxidant activity was assessed through DPPH and ABTS radical scavenging assays. Results demonstrated that all tested compounds exhibited dose-dependent antioxidant activity with the highest activity observed at 1000 µM. Among the series, compound 000A demonstrated the strongest antioxidant activity achieving 55.7% scavenging in the DPPH assay and 39.9% in the ABTS assay although its efficacy remained lower compared to the reference standard ascorbic acid. Structural analysis indicated that unsubstituted aromatic rings enhanced radical stabilization, while electron-withdrawing substituents and steric hindrance limited its activity. In conclusion, arylated thiosemicarbazone derivatives, particularly compound 000A, demonstrates a promising scaffold for the development of anti-aging cosmeceuticals. Furthermore, these findings highlight the importance of structural features in modulating compounds to improve its biological activity.
Key Words: Thiosemicarbazone; antioxidant; skin-aging
Abstract: Fish biodiversity and ecological health in Iligan Bay, Northern Mindanao, were assessed through analysis of species composition, catch abundance, and catch per unit effort (CPUE). Monthly landing surveys conducted from April to August 2025 at Linamon, Calangahan, and Manticao recorded twelve fish species from seven families, including Scombridae, Clupeidae, Engraulidae, Balistidae, Belonidae, Mugilidae, and Carangidae. Results revealed Bali sardine (Sardinella lemuru) as the most abundant species (40.70%), followed by anchovy (Encrasicholina oligobranchus, 13.43%) and bigeye scad (Selar crumenophthalmus, 11.33%). The dominance of these small pelagic fishes indicates a shift in catch composition from historically larger, high-trophic-level species to smaller, fast-growing species, reflecting national patterns of overfishing and ecosystem decline. CPUE values showed spatial variation: Sigpaw and Gillnets yielded the highest catches in Calangahan, while Castnets were more productive in Linamon and Punta Silum. These outcomes highlight the influence of gear selectivity, habitat conditions, and localized fishing pressure. The heavy reliance on small pelagic resources underscores the vulnerability of small-scale fishers to declining stocks and competition with commercial fleets. The findings provide an important baseline for sustainable fisheries management in Iligan Bay, emphasizing the need for effective monitoring, gear regulation, and habitat conservation to secure biodiversity and the livelihoods of fishers.
Key Words: ligan Bay, fish composition, catch per unit effort, small pelagic fisheries
Abstract: Orthoptera species are effective bioindicators due to their sensitivity to environmental changes, particularly those linked to climate change, making their acoustic behavior a reliable measure of ecosystem health. Recent advancements in Artificial Intelligence, particularly in Machine Learning, enabled automated detection and classification of these species through their bioacoustics signals. The WaveNet model, which processes raw audio and learns to distinguish the unique waveforms of different species, was used in this study. This effectively captures temporal patterns in sound, featuring causal and dilated convolutions that enable accurate species classification. WaveNet has achieved a precision, recall, and F1-score of 98.0%. The WaveNet model was successfully deployed on a Jetson Nano, a compact edge computing device equipped with a MEMS microphone, allowing real-time recording, processing, and analysis of insect sounds directly in the field.
Key Words: Orthoptera species; Machine Learning; Edge Computing Device; Jetson Nano; WaveNet
Abstract: This study investigated seeded magnesium carbonation for mineral-based CO2 capture. In a semi-batch reactor set-up, with optimal operational parameters identified: high initial carbonate (15 mM), pH 10, a 1:1 magnesium to carbonate ratio, and 200 rpm stirring, all enhancing reaction kinetics and granule formation. Subsequently, in a fluidized bed reactor (FBR) application, increasing the seed dose improves carbonate removal but diminishes granulation due to excessive nucleation, highlighting the need to optimize seed load for balanced efficiency and granule size. With comprehensive product characterization (FTIR, SEM, TGA, XRD), confirmed hydrated magnesium carbonate synthesis, primarily well-ordered hydromagnesite. This product exhibited unique hierarchical lamellar morphology and a three-stage decomposition, affirming its stability for long-term CO2 storage. Experimental results consistently validated thermodynamic predictions from Visual MINTEQ, reinforcing speciation modeling reliability and establishing key trends in reaction efficiency, product morphology, and process behavior. This research provides essential baseline data for future optimization and scale-up of seeded magnesium carbonation in FBRs, significantly advancing mineral-based carbon capture technologies.
Key Words: carbon sequestration; magnesium carbonation; CO2 capture; fluidized bed reactor; mineral carbonation
Abstract: Composite materials consist of a matrix and a filler, which, although immiscible, work synergistically to enhance strength and reduce weight, making them ideal for portable structural applications. Polymers are commonly used but often lack the required mechanical strength. To address this limitation, CerMetaCS, a ceramic–metal composite, was developed to enhance the performance of ceramic–polymer systems. Ceramic inserts from mining silt waste, with a high modulus of rupture, were used as fillers in an aluminum matrix for ballistic applications. Two fabrication routes were tested: investment casting and permanent mold. Investment casting failed to form complete layers, making the permanent mold a more suitable method for CerMetaCS fabrication. Characterization confirmed the suitability of local Nickel and Gold Mine Wastes (high Fe2O3, SiO2) as reinforcement. Ballistic tests showed ceramic-reinforced composites outperformed monolithic aluminum, demonstrating both enhanced impact resistance and a sustainable approach to waste valorization.
Key Words: cermet; composite materials; ceramic-metal composite; mining wastes; sustainable materials; waste valorization
Abstract: In the Philippines, the hot and humid climate makes natural ventilation essential, particularly since many households rely on single-sided façades and cannot afford air-conditioning. A widely used passive solution is the wing wall, which channels outdoor wind into the living space to improve airflow and cooling. However, conventional wing walls are inherently limited: their performance depends heavily on wind speed, direction, and installation angle, meaning one fixed design cannot ensure consistent ventilation. To address this challenge, our project introduces a data-driven, adaptive wing wall window that automatically adjusts in real time to changing wind conditions. The study begins with controlled wind-tunnel experiments that reproduce atmospheric boundary layer (ABL) behavior. Using the tracer gas method, we evaluate ventilation effectiveness and then construct a prototype. Experimental results are used to train an artificial neural network (ANN), which generates predictive airflow response curves. These predictions are further validated with CFD simulations before being integrated into the automated prototype. The expected outcome is an intelligent, responsive window system that not only enhances indoor air quality and comfort but also reduces reliance on energy-intensive air-conditioning. By aligning passive design with machine learning, the project aims to deliver a scalable solution for healthier and more sustainable homes in the Philippines.
Key Words: Wing wall, Wing wall window, Automated adjustable wing wall window prototype, Ventilation, Single-sided ventilation, CFD, Air Change Rate, Purging Flow Rate
Abstract: The depletion of high-grade gold ores and the environmental impacts of traditional cyanidation have prompted the exploration of alternative gold recovery methods. Inspired by the previous study of Zoleta et al. (2023), which demonstrated the use of aluminum powder as a cementation agent for selective gold recovery, this research investigates the use of cast aluminum derived from recycled cans as a cost-effective and safer alternative to zero-valent aluminum powder for recovering gold from refractory gold ores using copper ammoniacal thiosulfate solution. Two anodic cementation reactor prototypes were designed using SOLIDWORKS and fabricated through sand casting. The experiments examined the effects of reactor design, agitation speed, cementation time, and iron oxide addition on gold recovery selectivity. Gold and copper recoveries were determined using Inductively Coupled Plasma Atomic Emission Spectroscopy (ICP-AES), while the surface morphology and elemental composition of the iron oxide before and after cementation were analyzed using Scanning Electron Microscopy with Energy-Dispersive X-ray Spectroscopy (SEM-EDS). Results showed that Au recovery remained consistently high, ranging from 97.19% to 98.17%. Notably, the A1B2R2 configuration—combining low agitation, extended contact time, and Reactor 2—achieved the lowest Cu recovery at 26.44%, indicating strong selectivity toward gold. These findings demonstrate the practical potential of using cast aluminum reactors made from recycled cans for safer, selective, and cost-effective gold recovery from refractory ores.
Key Words: Selective Cementation; Refractory Gold Ores; Cast Aluminum Reactor; Ammoniacal Thiosulfate; Gold Recovery
Abstract: This study explores the readiness of two barangays in Iligan City to adopt smart village initiatives using the Technology–Organization–Environment (TOE) framework. A qualitative case study design was employed, drawing on semi-structured interviews with barangay officials and secondary data. The findings show that while both barangays have started digital initiatives, differences emerge in their technological capacity, organizational structures, and environmental support. Barangay 1, with its larger population and agricultural-business profile, has invested in advanced ICT tools and partnerships, while Barangay 2, a smaller coastal barangay, remains in a transitional phase but has identified ambitious plans for ICT-based services. Common challenges include limited budgets, weak institutionalization of ICT roles, and dependency on external actors. The study contributes to the growing literature on smart villages by highlighting how local context shapes
readiness and by emphasizing the need for integrated strategies that combine infrastructure,
human capacity, and multi-level governance support.
Key Words: smart village; readiness; case study; TOE framework
Abstract: Goat livestock plays a vital role in the economy by providing milk and meat, while also supporting household nutrition and livelihoods, particularly among the poor and smallholder farmers. Despite their importance, goats are highly susceptible to tick infestations, which not only cause direct harm, such as irritation and anemia, but also facilitate the transmission of tick-borne pathogens like Anaplasma species, the causative agents of anaplasmosis. In the Philippines, molecular studies on Anaplasma infections in goats remain limited and have largely focused on major cities, with no reported detection of Anaplasma directly from goat-associated ticks. To address this gap, this study screened DNA extracted from goat blood using conventional polymerase chain reaction (PCR) targeting the Anaplasma 16S rRNA gene. Of the 30 goat blood samples tested, 3.33% (1/30) were positive for Anaplasma. Phylogenetic analysis revealed a close relationship to A. phagocytophilum, and further genetic comparison showed similarity to the Ap-ha strain, a major variant of A. phagocytophilum that are known to be associated with humans. However, further studies are necessary to confirm its precise identity and to rule out the possibility that it represents a novel or unclassified Anaplasma species. This study provides the first molecular evidence of Anaplasma infection in goats from Northern Mindanao, Philippines, and offers valuable insights into the presence of tick-borne pathogens affecting livestock in the region.
Key Words: anaplasmosis, Ap-ha strain, phylogenetic analysis, tick-borne pathogens, 16S rRNA
Abstract: Lake Buluan, the third-largest lake in the Philippines, sustains rich aquatic biodiversity and supports extensive aquaculture. However, decades of anthropogenic pressures, including domestic wastewater, aquaculture effluents, and agricultural runoff, have degraded water quality. This study assessed morphologically, the composition and distribution of freshwater diatoms across six stations inside and outside fish pens to evaluate their potential as bioindicators of ecological change. Nineteen species were recorded, with 11 present in both inside (IFB) and outside (OFB) fish pens. Dominant taxa—Nitzschia serpentiraphe, Gomphonema montanum, and Aulacoseira islandica—occurred at nearly all stations and are linked to nutrient-rich sediments and organic pollution. Site-specific patterns emerged: Nitzschia liebethruthii dominated IFB1 and IFB3 but was absent in IFB2 and most OFB sites, whereas Nitzschia inconspicua showed the opposite trend. The exclusive occurrence of Eunotia monodon and Cymbella tumida in OFB stations suggests more acidic or oligotrophic conditions outside enclosures. Rare taxa (Sellaphora sp., Grammatophora angulosa) contributed to richness in non-enclosed areas. Moreover, next-generation sequencing (NGS) data confirmed the dominance of Nitzschia spp., indicating mild environmental stress and ecological plasticity which is, typical for tropical shallow lakes. Findings underscore diatom monitoring as a sensitive, cost-effective tool for assessing aquaculture impacts and advocate its integration into freshwater ecosystem management.
Key Words: diatom, lake, bioindicators, aquaculture
Abstract: This study investigates the extraction of calcium oxide (CaO) from waste mussel shells (Mytella strigata) as a precursor for synthesizing bioceramics, specifically hydroxyapatite (HAp). Mussel shells, a byproduct of the seafood industry, are rich in minerals, particularly calcium. Additionally, they contain a significant amount of calcium carbonate (CaCO3), which can be thermally decomposed into calcium oxide through calcination at temperatures ranging from 700°C to 1000°C. Consequently, innovation is essential to maximize the utilization of mussel shells. The extracted CaO serves as a key raw material in the synthesis of bioceramics, which are recognized for their biocompatibility, bioactivity, and applications in medical fields such as bone prosthetics and tissue engineering. Characterization techniques like X-ray fluorescence (XRF) and scanning electron microscopy (SEM) were employed to ensure the purity and suitability of the calcium oxide for bioceramic production. This process provides a sustainable, low-cost alternative to traditional methods of obtaining calcium precursors while also promoting the recycling of waste materials. The study highlights the potential of utilizing waste mussel shells as a renewable source for calcium oxide, contributing to the utilization of hydroxyapatite non-medical applications.
Key Words: waste mussel shells; calcium oxide; calcium carbonate; morphology; composition
Abstract: Amid growing environmental concerns and biomass waste accumulation, this study aims to valorize cassava pulp—a readily available agricultural by-product in the Philippines—by producing nanocrystalline cellulose (NCC), a high-value material with broad industrial applications and sustainability potential. This study explores the synthesis and characterization of NCC extracted from waste cassava pulp sourced in Northern Mindanao, Philippines. Extraction was performed via mixed acid hydrolysis using formic acid and sulfuric acid, following alkaline pretreatment with sodium hydroxide and bleaching with sodium hypochlorite. The effects of acid concentration, temperature (70–90°C), and hydrolysis time (1–6 hours) on extraction yield were investigated. Results showed that increasing these parameters initially improved yield, but excessive values led to a decline. Optimization yielded the most favorable conditions at 71 wt% formic acid, 77°C, and 3.6 hours, achieving an extraction yield of 67.272%± 2.295%. FTIR confirmed successful removal of lignin and hemicellulose, while SEM and dynamic light scattering (DLS) revealed nano-sized cellulose particles ranging from 15 nm to 687 nm.
Key Words: nanocrystalline cellulose; mixed acid hydrolysis; waste cassava pulp; supercapacitor; energy storage
Abstract: Incorporating nanoscale reinforcements into polymer matrices offers an effective way to enhance the multifunctional performance of polymer nanocomposites. Carbon-based nanomaterials (CNMs) are widely explored for this purpose because of their exceptional strength, stability, and large interfacial surface area that enable efficient stress transfer. Among them, diamond nanothreads (DNTs) have attracted attention for their one-dimensional sp³-bonded framework and hydrogen-terminated surfaces, which impart remarkable tensile strength, stiffness, and torsional resistance. Extending this concept, carbon nitride nanothreads (CNNTHs) have emerged as new candidates. The incorporation of nitrogen atoms enhances their structural versatility and narrows their electronic band gaps, making them attractive for designing polymer nanocomposites that combine robust mechanical properties with tunable electronic properties. This study employs first-principles simulations to explore the interfacial interactions and electronic properties of CNNTH/polymer nanocomposites. Cellulose and epoxy matrices were modeled in various orientations relative to CNNTHs. Charge Density Difference (CDD) and Electron Localization Function (ELF) analyses revealed charge redistribution primarily along the interface, with no ELF overlap, indicating interactions dominated by van der Waals forces. Electronic structure calculations further showed a 1 eV reduction in band gap compared to DNT/polymer systems. These results demonstrate CNNTHs’ potential as reinforcements for high-performance polymer nanocomposites in advanced structural systems and flexible electronics.
Key Words: polymer; CNNTH; nanocomposites; electronic properties